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Direct, Metal-Free Synthesis of Benzyl Alcohols and Deuterated Benzyl Alcohols from p-Toluenesulfonylhydrazones Using Water as Solvent

  作者 GARCIAMUNOZ ANGEL; ORTEGAARIZMENDI ALDO I; GARCIACARRILLO MARIO A; DIAZ EDUARDO; GONZALEZRIVAS NELLY; CUEVASYANEZ ERICK  
  选自 期刊  Synthesis;  卷期  2012年44-14;  页码  2237-2242  
  关联知识点  
 

[摘要]A novel library of diverse alcohols was synthesized by metal-free couplings of diazoalkanes derived from p-toluenesulfonylhydrazones to water under reflux and microwave conditions, in high yields. In addition, this protocol was successfully applied in the synthesis of deuterium-labeled alcohols using deuterium oxide.

 
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