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Cycloadditions of Allylsilanes - Part 22. Stereoselective Synthesis of Cyclopentanes and Cyclobutanes by Lewis Acid Promoted [3+2] and [2+2] Cycloadditions of Allylsilanes

  作者 SCHMIDT ARNDT W; KNOELKER HANSJOACHIM  
  选自 期刊  SYNLETT;  卷期  2010年-15;  页码  2207-2239  
  关联知识点  
 

[摘要]

The development of Lewis acid promoted [3+2] and [2+2] cycloadditions as a novel methodology for the stereoselective construction of cyclopentanes and cyclobutanes is described. Elegant applications of this methodology to the total synthesis of biologically active terpenoid natural products are presented.

 
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