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Phosphine-Catalyzed [3+2] Annulation of Cyanoallenes

  作者 KINDERMAN SAPE S; VAN MAARSEVEEN JAN H; HIEMSTRA HENK  
  选自 期刊  SYNLETT;  卷期  2011年-12;  页码  1693-1696  
  关联知识点  
 

[摘要]Cyanoallenes were successfully used in organophosphine-catalyzed [3+2]-type annulation to give cyano-substituted dihydropyrroles in good yield. Chiral phosphines were also screened, leading to some initial results in the asymmetric version of cyanoallene-based annulations.

 
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