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Synthesis of 1-Pentafluorosulfanyl-1,3-Dienes

  作者 HUSSTEDT WIBKE S; THRASHER JOSEPH S; HAUFE GUENTER  
  选自 期刊  SYNLETT;  卷期  2011年-12;  页码  1683-1686  
  关联知识点  
 

[摘要]A series of pentafluorosulfanyl-substituted dienes has been synthesized from 3-pentafluorosulfanyl-prop-2-enal employing either Grignard reactions with subsequent dehydration or by oxidation of 1-pentafluorosulfanyl-alk-1-en-3-ols to the corresponding ketones and subsequent Wittig-type olefinations.

 
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