Iodine-catalyzed tandem synthesis of terminal acetals and glycol mono esters from olefins

[摘要]：A new metal-free protocol is described for the synthesis of terminal acetals by tandem oxidative rearrangement of olefins using oxone as an oxidant in the presence of iodine. Moreover, a one-pot procedure for the preparation of glycol mono esters from olefins is also presented for the first time using the same reagent system.

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