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Studies toward the Total Synthesis of Carolacton

  作者 SABITHA GOWRAVARAM; SHANKARAIAH K; PRASAD M NAGENDRA; YADAV JHILLU S  
  选自 期刊  Synthesis;  卷期  2013年45-2;  页码  251-259  
  关联知识点  
 

[摘要]An efficient synthesis of the C1-C19 segment of carolacton is described, starting from D-ribose, (-)-beta-citronellene and a homopropargylic alcohol, and which employs a Nozaki-Hiyama-Kishi (NHK) coupling as the key step. Other important steps are cross-metathesis and Evans aldol reactions.

 
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