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Direct access to pyrazolo(benzo)thienoquinolines. Highly effective palladium catalysts for the intramolecular C-H heteroarylation of arenes

  作者 CHURRUCA FATIMA; HERNANDEZ SUSANA; PEREA MARIA; SANMARTIN RAUL; DOMINGUEZ ESTHER  
  选自 期刊  Chemical Communications;  卷期  2013年49-14;  页码  1413-1415  
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[摘要]A short and atom-efficient strategy to obtain a series of pyrazolo(benzo)thienoquinolines is developed. Alternative catalytic systems for the key intramolecular direct heteroarylation of arenes are presented and include the first example of C-H (hetero)arylation of (hetero)arenes catalyzed by very low catalyst loadings of a palladium source.

 
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