Synthesis of Indoles by Copper-Catalyzed Heteroannulation of o-Aminophenylboronic Acid Pinacol Esters with beta-Keto Esters
[摘要]:Copper-catalyzed coupling of o-aminophenylboronic acid pinacol esters with beta-keto esters afforded, under mild base-free oxidative conditions, 2,3-disubstituted indoles featuring a key Chan-Lam-type carbon-carbon bond-forming reaction.
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