Facile and Efficient Hypervalent Iodine(III)-Mediated meso-Functionalization of Porphyrins.

[摘要]：Highly facile and efficient synthesis of a variety of meso-functionalized porphyrins was accomplished by PhI(OAc)2-NaAuCl4 mediated direct nucleophilic substitution reactions of [5,10,15-triphenylporphyrinato]zinc(II) (Zn1) with different amines and thiophenols. When [5,15-dibromo-10,20-diphenylporphyrinato]zinc(II) (Zn12) was used as the starting porphyrin under similar conditions, the double nucleophilic substitution products were obtained in good yields.

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