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A Synthesis of (-)-Mintlactone.

  作者 Bates, Roderick W.;Sridhar, S.;  
  选自 期刊  Journal of Organic Chemistry;  卷期  2008年73-20;  页码  8104-8105  
  关联知识点  
 

[摘要]Mintlactone (I) is synthesized in a concise and efficient way by using a highly diastereoselective intramol. propargylic Barbier reaction, followed by an allenol cyclocarbonylation. Tin(II) chloride is found to be the most effective reagent for the Barbier reaction.

 
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