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High-yield synthesis of substituted and unsubstituted pyridinium salts containing a 4-oxothiazolidine moiety.

  作者 Baranac-Stojanovic, Marija;Tatar, Jovana;Kleinpeter, Erich;Markovic, Rade;  
  选自 期刊  Synthesis;  卷期  2008年-13;  页码  2117-2121  
  关联知识点  
 

[摘要]A new series of unsubstituted and substituted pyridinium salts bearing a 4-oxothiazolidinyl moiety was prepd. by an efficient rearrangement of 2-(1-bromoalkylidene)thiazolidin-4-ones. The process is based on three steps, namely carbon-bromine cleavage, bromine transfer, and substitution, each induced by pyridine or its derivs., acting as base and reactant.

 
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