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Chirality transcription and amplification by [2]pseudorotaxanes

  作者 KUWAHARA SHUNSUKE; CHAMURA RIE; TSUCHIYA SHO; IKEDA MARI; HABATA YOICHI  
  选自 期刊  Chemical Communications;  卷期  2013年49-22;  页码  2186-2188  
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[摘要]Chirality transcription and amplification by the formation of chiral [2] pseudorotaxanes by an achiral crown ether having the 2',2 ''-quaterphenyl group and chiral sec-ammonium ions are reported. It was revealed that the absolute configurations of the chiral sec-ammonium ions can be detected directly from the CD spectra of the chiral [2] pseudorotaxanes.

 
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