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[摘要]：The results of a thermogravimetric study into the dry fluorination of molybdenum disilicide, MoSi2, using hydrogen fluoride and dilute fluorine gas as fluorinating agents are reported. The reaction between molybdenum disilicide and fluorine follows the thermodynamically preferred route, viz, the formation of the volatile molybdenum hexafluoride along with gaseous silicon tetrafluoride, with the reaction starting just below 200 degrees C. The reaction with hydrogen fluoride yields solid molybdenum metal and gaseous silicon tetrafluoride, similarly thermodynamically predicted, above 250 degrees C. No reaction is observed at low temperatures where solid molybdenum trifluoride is expected to form. The results of a kinetic analysis of the data for the reaction with hydrogen fluoride are reported. In the range 250-450 degrees C the kinetics are chemical reaction controlled. Above this, up to 700 degrees C, the rate is controlled by diffusion through the stagnant gas films surrounding the solid particles. Evidence for a third, un-quantified, high-temperature mechanism is given. (c) 2012 Elsevier B.V. All rights reserved. |
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