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Room-Temperature Compression-Induced Diamondization of Few-Layer Graphene

  作者 Barboza, APM; Guimaraes, MHD; Massote, DVP; Campos, LC; Neto, NMB; Cancado, LG; Lacerda, RG; Chacham, H; Mazzoni, MSC; Neves, BRA  
  选自 期刊  ADVANCED MATERIALS;  卷期  2011年23-27;  页码  3014-3014  
  关联知识点  
 

[摘要]Experimental and theoretical evidence for compression-induced diamondization of few-layer graphene is reported. Ab initio calculations predict that hydroxyl groups stabilize the sp(3) hybridization of the two topmost carbon layers, creating a single layer of hydroxylated diamond, or diamondol, when graphene layers are compressed in the presence of water. Electric force microscopy measurements reveal a compression- induced charging inhibition of bilayer and multilayer graphene.

 
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