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Synergic Sedation of Sensitive Anions: Alkali-Mediated Zincation of Cyclic Ethers and Ethene

  作者 Kennedy, AR; Klett, J; Mulvey, RE; Wright, DS  
  选自 期刊  Science;  卷期  2009年326-5953;  页码  706-708  
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[摘要]Deprotonation of alkyl and vinyl carbon-hydrogen bonds for synthetic purposes is often hindered not merely by the need for an exceptionally strong base, but by the inherent instability of the resultant anion. Metalation of cyclic ethers adjacent to oxygen

 
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