Transition-Metal-Catalyzed Regioselective Arylation and Vinylation of Carboxylic Acids

[摘要]：Arene and heteroarene carboxylic acids undergo regioselective arylation and vinylation reactions at the positions ortho (cine) and ipso to their carboxyl function under transition-metal catalysis; these reactions are accompanied by carbon-hydrogen and carbon-carbon bond cleavages, respectively. Recent progress in this area is summarized in this article. 1 Introduction 2 ortho- (cine-) Arylation 3 ortho- (cine-) Vinylation 4 ipso-Arylation 5 ipso-Vinylation 6 Conclusions

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