Formal Total Synthesis of (-)-5,6-Dihydrocineromycine B

[摘要]：An efficient and highly convergent formal total synthesis of the 14-membered macrolide (-)-5,6-dihydrocineromycine B is achieved. Key reaction sequences include a Sharpless asymmetric epoxidation followed by esterification for the formation of a fully functionalized acyclic precursor, Corey-Bakshi-Shibata reduction, and ring-closing metathesis, respectively.

[全文传递流程]：

一般上传文献全文的时限在1个工作日内