Efficient Synthesis of alpha-Tertiary alpha-Silylamines from Aryl Sulfonylimidates via One-Pot, Sequential C-Si/C-C Bond Formations

[摘要]：An efficient and flexible route for the synthesis of alpha-tertiary (alpha,alpha-dibranched) alpha-silylamines via sequential reactions of sulfonylimidates using readily available phenyldimethylsilyllithium and Grignard reagents is described. The procedure allows successive formation of C-Si/C-C bonds In a single flask.

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