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Reaction of Benzyne with Salicylaldehydes: General Synthesis of Xanthenes, Xanthones, and Xanthols.

  作者 Okuma, Kentaro;Nojima, Akiko;Matsunaga, Nahoko;Shioji, Kosei;  
  选自 期刊  Organic Letters;  卷期  2009年11-1;  页码  169-171  
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[摘要]The reaction of salicylaldehydes with benzyne prepd. from o-trimethylsilylphenyl triflate and CsF gave xanthenes and xanthones. When the reaction was carried out under basic conditions, 9-hydroxyxanthenes (xanthols) were obtained in good yields.

 
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