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Homologation of Boronic Esters with Lithiated Epoxides for the Stereocontrolled Synthesis of 1,2- and 1,3-Diols and 1,2,4-Triols.

  作者 Vedrenne, Emeline;Wallner, Olov A.;Vitale, Maxime;Schmidt, Frank;Aggarwal, Varinder K.;  
  选自 期刊  Organic Letters;  卷期  2009年11-1;  页码  165-168  
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[摘要]Lithiated epoxides react stereospecifically with boronic esters to give syn-1,2-diols, a process that can be used iteratively to create triols contg. four stereogenic centers.

 
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