Enantioselective synthesis of (R)-a-(p-nitroaryl)prolines via oxidative nucleophilic substitution of hydrogen in nitroarenes.
[摘要]:Optically pure (R)-a-(p-nitroaryl)prolines are synthesized via oxidative nucleophilic substitution of hydrogen in nitroarenes using chiral carbanion of L-proline protected as N,O-acetal of pivalaldehyde.
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