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A User-Friendly Procedure for the Preparation of Secondary Alkyl Chlorides

  作者 CAHIEZ GERARD; LEFEVRE NICOLAS; POIZAT MAEL; MOYEUX ALBAN  
  选自 期刊  Synthesis;  卷期  2013年45-2;  页码  231-236  
  关联知识点  
 

[摘要]Secondary alkyl chlorides have been efficiently prepared from secondary alkyl sulfonates under mild and user-friendly conditions. The exchange reaction was generally performed by using benzyltributylammonium chloride in acetone (reflux, 30 min). Yields are excellent from functionalized, base-sensitive and hindered secondary alkyl sulfonates.

 
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