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Synthesis of Azacalixarenes through Dihydrobenzoxazine Derivatives of Phenols

  作者 TAKEMURA HIROYUKI; TAKAHASHI ASUKA; SUGA HARUKA; FUKUDA MIKA; IWANAGA TETSUO  
  选自 期刊  European Journal of Organic Chemistry;  卷期  2011年-17;  页码  3171-3177  
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[摘要]A new series of azacalix[n]arenes were synthesized by the reaction between the benzoxazine derivatives of phenols and the phenol oligomers. The reaction should be carried out at 40-80 degrees C, because scrambling of the phenol units occurs at higher temperatures. The appropriate reaction conditions afforded the desired azacalixarene which was asymmetrical along the N center dot center dot center dot N' or N center dot center dot center dot CH2 axis.

 
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