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[摘要]:A new series of azacalix[n]arenes were synthesized by the reaction between the benzoxazine derivatives of phenols and the phenol oligomers. The reaction should be carried out at 40-80 degrees C, because scrambling of the phenol units occurs at higher temperatures. The appropriate reaction conditions afforded the desired azacalixarene which was asymmetrical along the N center dot center dot center dot N' or N center dot center dot center dot CH2 axis. |
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