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Anthradithiophene Derivatives Substituted at the 2,8-Positions by Formyl and Triphenylamine Units: Synthesis, Optical, and Electrochemical Properties

  作者 BALANDIER JEANYVES; SEBAIHI NOHAM; BOUDARD POL; LEMAUR VINCENT; QUIST FLORENCE; NIEBEL CLAUDE; STAS SARA; TYLLEMAN BENOIT; LAZZARONI ROBERTO; CORNIL JEROME; GEERTS YVES HENRI  
  选自 期刊  European Journal of Organic Chemistry;  卷期  2011年-17;  页码  3131-3136  
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[摘要]The synthesis and characterization of two new anthradithiophene (ADT) derivatives substituted by thiophenyl or 2-octylthiophenyl units at the 5,11-positions and donor (triphenylamine) or acceptor (aldehyde functions) moieties at the 2,8-positions of their backbone are described. Optical measurements were performed to evaluate the effect of electron-rich/-poor substituents on their stability towards photo-oxidation and were supported by quantum chemical calculations and cyclic voltammetry experiments.

 
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