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Exclusive Photodimerization Reactions of Chromone-2-carboxylic Esters Depending on Reaction Media

  作者 SAKAMOTO MASAMI; YAGISHITA FUMITOSHI; KANEHIRO MASAYUKI; KASASHIMA YOSHIO; MINO TAKASHI; FUJITA TSUTOMU  
  选自 期刊  Organic Letters;  卷期  2010年12-20;  页码  4435-4437  
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[摘要]The irradiation of chromone-2-carboxylic esters resulted in the stereo- and regioselective formation of C-2 chiral anti-HR dimers from the triplet excited state. On the contrary, photolysis in the solid-state gave anti-HT dimers exclusively controlled by molecular arrangement in the crystal

 
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