SYNTHESIS OF (-)-UNTENOSPONGIN C, A C(21) FURANOTERPENE ISOLATED FROM THE OKINAWAN SPONGE HIPPOSPONGIA SP.

[摘要]：Starting with (R)-(+)-citronellol (5), the first enantioselective synthesis of (-)-untenospongin C (1), a C(21) furanoterpene isolated from a marine sponge Hippospongia sp., has been achieved, the present synthesis indicating the absolute configuration of 1 as S.

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