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"Click-Fluors": Synthesis of a Family of pi-Conjugated Fluorescent Back-to-Back Coupled 2,6-Bis(triazol-1-yl)pyridines and Their Self-Assembly Studies

  作者 CHANDRASEKHAR NAISA; CHANDRASEKAR RAJADURAI  
  选自 期刊  Journal of Organic Chemistry;  卷期  2010年75-14;  页码  4852-4855  
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[摘要]This paper presents an eight-step synthetic method for the preparation of a series of new back-to-back coupled 2,6-bis(triazol-1-yl)pyridine (btp) molecules (L1-L3). These L1-L3 molecules displayed fluorescent emission at 381, 381, and 457 nm, respectively. We also demonstrated the self-assembly of these fluorescent molecules with Eu3+ ions to obtain Eu3+ centered red-orange luminescent solids via "antenna effect".

 
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