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Iron-Catalyzed, Directed Oxidative Arylation of Olefins with Organozinc and Grignard Reagents

  作者 ILIES LAUREAN; OKABE JUN; YOSHIKAI NAOHIKO; NAKAMURA EIICHI  
  选自 期刊  Organic Letters;  卷期  2010年12-12;  页码  2838-2840  
  关联知识点  
 

[摘要]Chelation-controlled arylation of olefins with organozinc or Grignard reagents proceeds in the presence of an iron catalyst, under mild conditions and typically without the need of external ligands, to afford substituted olefins in high yield and with complete regio- and stereocontrol.

 
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