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A dinuclear platinum complex featuring the diboran(4)-1,2-diyl ligand in a mu(2)-bridging coordination mode

  作者 BRAUNSCHWEIG HOLGER; BERTERMANN RUEDIGER; DAMME ALEXANDER; KUPFER THOMAS  
  选自 期刊  Chemical Communications;  卷期  2013年49-24;  页码  2439-2441  
  关联知识点  
 

[摘要]A novel mu(2)-bridging coordination mode of the diboran(4)-1,2-diyl ligand was unveiled for dinuclear 1, in which two Pt(II) centers are connected by the diboran(4)yl moiety. Prolonged heating resulted in the unprecedented reductive elimination of the haloborane from one Pt(II) center to afford mononuclear 2.

 
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