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NEW INDOLE ALKALOIDS FROM ALSTONIA MACROPHYLLA

  作者 DEGUCHI JUN; SHOJI TOMOKAZU; HIRASAWA YUSUKE; RAHMAN ABDUL; SHIROTA OSAMU; MORITA HIROSHI  
  选自 期刊  Heterocycles;  卷期  2012年86-2;  页码  1603-1610  
  关联知识点  
 

[摘要]Alkaloidal investigations of Alstonia macrophylla led to the isolation of a new 3-alkylpyridinium-indole-2-carboxylate scaffold alkaloid, N(1)-demethyl-7-methoxyikirydinium A (1) and a yohimbane-type alkaloid, 10-methoxydihydrosempervirine (2), and two strychane-type alkaloids, 17-carboxylcompactivervine N-oxide (3) and 17-carboxylalstovine N-oxide (4). Their structures were elucidated by NMR spectral analysis using 2D techniques and CD spectra.

 
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