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Synthesis of diazonium (perfluoroalkyl) benzenesulfonylimide zwitterions

  作者 MEI HUA; VANDERVEER DON; DESMARTEAU DARRYL D  
  选自 期刊  Journal of Fluorine Chemistry;  卷期  2013年145-1;  页码  35-40  
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[摘要]The synthesis and properties of diazonium (perfluoroalkyl) benzenesulfonylimide (PFSI) zwitterions are described. The general procedures for the diazonium PFSI zwitterions involve three steps: (1) a coupling reaction, (2) a reduction reaction and (3) a diazotization reaction. These novel diazonium PFSI zwitterions represent a new versatile class of remarkably stable diazonium materials with potential for modification of carbon supports for electrodes in proton exchange membrane (PEM) fuel cells. (c) 2012 Elsevier B.V. All rights reserved.

 
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