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Unusual para-substituent effects on the intramolecular hydrogen-bond in hydrazone-based switches

  作者 SU XIN; LOKOV MAERT; KUETT AGNES; LEITO IVO; APRAHAMIAN IVAN  
  选自 期刊  Chemical Communications;  卷期  2012年48-85;  页码  10490-10492  
  关联知识点  
 

[摘要]A "V"-shaped Hammett plot shows that resonance-assisted hydrogen bonding does not dictate the strength of the intramolecular hydrogen bond in the E isomers of hydrazone-based switches because it involves an aromatic pyridyl ring.

 
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