个性化文献订阅>期刊> Organic Letters
 

Rhodium-Catalyzed Activation of C(sp(3))-X (X = Cl, Br) Bond: An Intermolecular Halogen Exchange Case

  作者 WANG JIANPING; TONG XIAOFENG; XIE XIAOMIN; ZHANG ZHAOGUO  
  选自 期刊  Organic Letters;  卷期  2010年12-23;  页码  5370-5373  
  关联知识点  
 

[摘要]A RhCl(PPh3)(3)-catalyzed halogen-exchange reaction between allyl and alkyl halides with beta-H atoms was observed. The possible mechanism of the reaction involves oxidative addition and reductive elimination of the C(sp(3))-X bonds, which is not common in organometallic chemistry.

 
      被申请数(0)  
 

[全文传递流程]

一般上传文献全文的时限在1个工作日内