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Hydrazone-Promoted Sonogashira Coupling Reaction with Aryl Bromides at Low Palladium Loadings

  作者 MINO TAKASHI; SUZUKI SAORI; HIRAI KIMINORI; SAKAMOTO MASAMI; FUJITA TSUTOMU  
  选自 期刊  SYNLETT;  卷期  2011年-9;  页码  1277-1280  
  关联知识点  
 

[摘要]The Sonogashira coupling reaction of aryl bromides with a variety of terminal alkynes in DMSO at 125 degrees C gave internal arylated alkynes using low-loaded Pd(acac)(2) with hydrazone as a ligand and CuI as the co-catalyst in good yields.

 
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