Activation of dichloromethane by a V(III) thiolate complex: an example of S-based nucleophilic reactivity in an early transition metal thiolate

[摘要]：A V-III thiolate complex activated C-Cl bond in dichloromethane via S-based nucleophilic attack. The reaction products, a V-III-Cl species (major one) and a V-IV binding to a CH2 containing ligand (minor one) were obtained. The work demonstrates sulfur donors in the early-transition metal thiolates having strong nucleophilic characteristics.

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