Functional Group Tolerable Synthesis of Allylsilanes through Copper-Catalyzed gamma-Selective Allyl-Alkyl Coupling between Allylic Phosphates and Alkylboranes

[摘要]：A copper-catalyzed gamma-selective allyl-alkyl coupling between gamma-silylated allylic phosphates and alkylboron compounds (alkyl-9-BBN, prepared by hydroboration of alkenes with 9-BBN-H) produced allylsilanes. The reaction tolerated various functional groups in both the alkylboranes and the allylic phosphates, and afforded functionalized allylsilanes.

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