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Synthesis of the Structure Proposed for Natural Meliloester

  作者 DING LU; LI ZHONGHAN; LU XIAOWEI; WU YIKANG; LI YAN  
  选自 期刊  Synthesis;  卷期  2012年44-21;  页码  3296-3300  
  关联知识点  
 

[摘要]In an attempt to establish the absolute configuration of meliloester, a natural product isolated from Melilotus alba, the literature structure was synthesized in an enantiopure form. Unexpectedly, the H-1 and C-13 NMR data was completely incompatible with those reported for the natural product. The corresponding m-hydroxy isomer was also excluded as the structure for the natural product.

 
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