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Tuning Ion Conducting Pathways Using Holographic Polymerization

  作者 Smith, DM; Dong, B; Marron, RW; Birnkrant, MJ; Elabd, YA; Natarajan, LV; Tondiglia, VP; Bunning, TJ; Li, CY  
  选自 期刊  Nano Letters;  卷期  2012年12-1;  页码  310-314  
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[摘要]Polymer electrolyte membranes (PEMs) with high and controlled ionic conductivity are important for energy-related applications, such as solid-state batteries and fuel cells. Herein we disclose a new strategy to fabricate long-range ordered PEMs with tunable ion conducting pathways using a holographic polymerization (HP) method. By incorporating polymer electrolyte into the carefully selected HP system, electrolyte layers/channels with length scales of a few tens of nanometers to micrometers can be formed with controlled orientation and anisotropy; ionic conductivity anisotropy as high as 37 has been achieved.

 
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