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An Efficient and Highly Selective Method for the Synthesis of Cryptotackiene Derivatives Catalyzed by Iodine

  作者 WANG XIANGSHAN; ZHOU JIE; YIN MINGYUE; YANG KE; TU SHUJIANG  
  选自 期刊  Journal of Heterocyclic Chemistry;  卷期  2010年47-4;  页码  873-877  
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[摘要]A mild, efficient and highly selective approach to the synthesis of cryptotackiene derivatives via three-component reactions of 3-amino-9-ethylcarbazole and aromatic aldehydes with electron-rich alkenes, such as 2,3-dihydrofuran, or 3,4-dihydro-2H-pyran catalyzed by iodine in THF is reported. It is worth to note that only trans-products were obtained with high selectivity in good to high yields, which confirmed by X-ray diffraction analysis.

 
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