Palladium-Catalyzed Saegusa-Ito Oxidation: Synthesis of alpha,beta-Unsaturated Carbonyl Compounds from Trimethylsilyl Enol Ethers

[摘要]：Palladium-catalyzed Saegusa-Ito oxidation of trimethylsilyl enol ethers is possible using Oxone as a stoichiometric oxidant and sodium hydrogen phosphate as a buffer. Cyclic and acyclic enones as well as alpha,beta-unsaturated aldehydes are obtained in good to excellent yields.

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