Enzymatic Dynamic Kinetic Resolution of (+/-)-cis-N-(Alkoxycarbonyl)cyclopentane-1,2-diamines based on Spontaneous Racemization

[摘要]：Lipase B from Candida antarctica is an excellent catalyst for the enantioselective acetylation of different (+/-)-cis-N-(alkoxycarbonyl)cyclopentane-1,2-diamines. Depending on the alkoxycarbonyl group, a simple kinetic resolution (Boc-derivative) or an interesting dynamic kinetic resolution (DKR with Cbz-, Alloc, and ethoxycarbonyl derivatives) has been developed. Racemization for the DKR occurred due to the N,N' intramolecular migration of the alkoxycarbonyl group.

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