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Vanadium-salan catalyzed enantioselective ring opening of meso-epoxides with aromatic amines.

  作者 Sun, Jiangtao;Dai, Zhenya;Yang, Minghua;Pan, Xu;Zhu, Chengjian;  
  选自 期刊  Synthesis;  卷期  2008年-13;  页码  2100-2104  
  关联知识点  
 

[摘要]The first example of enantioselective ring-opening of meso-epoxides catalyzed by chiral oxovanadium(V)-salan complexes was reported. The reaction furnished 1,2-aminoalcs. in good yields and moderate to high enantioselectivities (up to 87%).

 
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