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Preparation of Pentafluorinated Phenyl-Monohydro[60]fullerenes

  作者 SHANG WENLI; ZHANG JIANMIN; CHEN XIAOLEI; ZOU YUANHAI; HE SHANSHAN; ZHAO JINGWEI; ZHU SHIZHENG  
  选自 期刊  Synthesis;  卷期  2012年44-16;  页码  2575-2578  
  关联知识点  
 

[摘要]Pentafluorinated phenyl-monohydro[60]fullerenes [C-60(Arf)(5)H] are synthesized in good yields via reaction of the corresponding fluorinated phenyl copper reagent, itself prepared in situ from the fluorinated phenyl Grignard reagent (ArfMgBr) and copper(I) bromide-dimethyl sulfide complex, with [60] fullerene (C-60) in 1,2-dichlorobenzene under a nitrogen atmosphere.

 
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