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Easy Access to Acetal-Spiroacetal-Enol Ethers by Tandem Dearomatization of a Furan Ring and Acetalization

  作者 YIN BIAOLIN; LAI JINQIANG; HUANG LI; ZHANG XIAOYU; JI FANGHUA  
  选自 期刊  Synthesis;  卷期  2012年44-16;  页码  2567-2574  
  关联知识点  
 

[摘要]A range of structurally novel acetal-spiroacetal-enol ethers were readily synthesized from 3-[5-(methoxymethyl)-2-furyl] propionaldehydes by dearomatization to form carbocations that were trapped intramolecularly by the formyl group with subsequent acetalization.

 
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