A cyanide and hydroxo-bridged nanocage: a new generation of coordination clusters

[摘要]：Combining serendipitously-formed hydroxo-clusters, [Co-3(II)(OH)-(piv)(4)(L)](+) (where L = MeCN or Hpiv), with assembling cyanide building block, [Fe-III(Tp)(CN)(3)](-), has led to an unprecedented architecture where polymetallic cobalt clusters and blocked tris-cyanide iron complexes define the apexes of a unique magnetic cubic nanocage.

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