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[摘要]:A novel mu(2)-bridging coordination mode of the diboran(4)-1,2-diyl ligand was unveiled for dinuclear 1, in which two Pt(II) centers are connected by the diboran(4)yl moiety. Prolonged heating resulted in the unprecedented reductive elimination of the haloborane from one Pt(II) center to afford mononuclear 2. |
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