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Kinetic Resolution of Racemic 2,3-Allenoates by Organocatalytic Asymmetric 1,3-Dipolar Cycloaddition

  作者 YU JIE; CHEN WEIJIE; GONG LIUZHU  
  选自 期刊  Organic Letters;  卷期  2010年12-18;  页码  4050-4053  
  关联知识点  
 

[摘要]The kinetic resolution of racemic 2,3-allenoates was realized via 1,3-dipolar cycloaddition by using a bisphosphoric acid catalyst, affording the optically active 2,3-allenoates and 3-methylenepyrrolidine derivatives in high yields and enantioselectivities.

 
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