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Squaramide-Based Reagent for Selective Chromogenic Sensing of Cu(II) through a Zwitterion Radical

  作者 SANNA ELENA; MARTINEZ LUIS; ROTGER CARMEN; BLASCO SALVADOR; GONZALEZ JORGE; GARCIAESPANA ENRIQUE; COSTA ANTONI  
  选自 期刊  Organic Letters;  卷期  2010年12-17;  页码  3840-3843  
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[摘要]A minimalist squaramide-based chemodosimeter for Cu2+ is described. Upon selective chelation to 2, Cu2+ induces the formation of a highly colored zwitterionic radical, which is kinetically stable for hours. The presence of a radical is confirmed by EPR and ESI-MS. It is then possible to use reagent 2 for visual and selective sensing of Cu2+ at neutral pH.

 
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