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Borylation on Benzo[1,2-b:4,5-b ']- and Naphtho[1,2-b:5,6-b ']dichalcogenophenes: Different Chalcogene Atom Effects on Borylation Reaction Depending on Fused Ring Structure

  作者 NAKANO MASAHIRO; SHINAMURA SHOJI; SUGIMOTO RYUSUKE; OSAKA ITARU; MIYAZAKI EIGO; TAKIMIYA KAZUO  
  选自 期刊  Organic Letters;  卷期  2012年14-21;  页码  5448-5451  
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[摘要]The direct borylation reactions of two types of alpha-silyl-protected acenedichalcogenophenes, i.e., benzo[1,2-b:4,5-b']- and naphtho[1,2-b:5,6-b']dichalcogenophenes, were examined, and it was observed that the reaction efficiency largely depends on the fused ring structure and chalcogenophene ring.

 
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