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A stable and strongly luminescent dinuclear Cu(I) helical complex prepared from 2-diphenylphosphino-6-methylpyridine

作者	CID JUANJOSE; MOHANRAJ JOHN; MOHANKUMAR MEERA; HOLLER MICHEL; ACCORSI GIANLUCA; BRELOT LYDIA; NIERENGARTEN IWONA; MOUDAM OMAR; KAESER ADRIEN; DELAVAUXNICOT BEATRICE; ARMAROLI NICOLA; NIERENGARTEN JEANFRANCOIS

选自	期刊 Chemical Communications; 卷期 2013年49-9; 页码 859-861

关联知识点

[摘要]：Treatment of 2-diphenylphosphino-6-methylpyridine (dpPyMe) with Cu(CH3CN)(4)BF4 afforded the stable dinuclear Cu(I) complex [Cu-2(mu-dpPyMe)(3)(CH3CN)](BF4)(2). This compound is a weak emitter in solution, however a remarkably high emission quantum yield (46%) has been found in a rigid matrix at room temperature.
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